If the built in attributes are not sufficient to validate your model data, then you can place your validation logic in a class derived from ValidationAttribute. In this example only odd numbers are valid values for a model member.
Custom Validation Attribute
public class OddNumberAttribute : ValidationAttribute
{
    protected override ValidationResult IsValid(object value, ValidationContext validationContext)
    {
        try
        {
            var number = (int) value;
            if (number % 2 == 1)
                return ValidationResult.Success;
            else
                return new ValidationResult("Only odd numbers are valid.");
        }
        catch (Exception)
        {
            return new ValidationResult("Not a number.");
        }            
    }
}
Model Class
public class MyModel
{
    [OddNumber]
    public int Number { get; set; }
}