Select 'Windows Forms Application' from Visual Basic Tab. You can rename it here if you need to.
Once you click 'OK', you will see this window:
Click on the 'Toolbox' tab on the left. The toolbar has 'auto-hide' option enabled by default. To disable this option, click the small symbol between the 'down arrow' symbol and the 'x' symbol, on the top-right corner of Toolbox window.
Get yourself familiar with the tools provided in the box. I have made a calculator interface by using buttons and a Textbox.
Click on the Properties tab (It is on the right side of the editor). You can change the Text property of a button, and the textbox to rename them. Font property can be used to alter the font of the controls.
To write the specific action for an event(eg. clicking on a button), double click on the control. Code window will open.
Enjoy your first creation in VB.Net!